ORIGINAL_ARTICLE
Removing Methyl Orange Molecules from Aqueous Medium by Magnetic Nanoparticles: Evaluating adsorption factors, isotherms, kinetics and thermodynamics
In this paper, Fe3O4 and MgFe2O4 as magnetic samples were successfully synthesized by coprecipitation and combustion methods, respectively, to be used for adsorption of toxic methyl orange molecules from the aqueous solution. Characteristics of the synthesized samples were evaluated using various analyses. The results of crystalline and surface bonding assessment confirmed the successful synthesis of both samples with an appropriate structure. Moreover, Fe3O4 presented higher magnetic properties and surface area as well as lower pore diameter than MgFe2O4 sample. However, the maximum adsorption of methyl orange was obtained for MgFe2O4 (56.54 mg/g) which was around three times of Fe3O4 in the same conditions. This may be related to larger pore diameter of MgFe2O4 and the ease of access to the internal surface of the adsorbent by the adsorbate molecules. Among the evaluated isotherms, the predicted Freundlich model showed well correlation with actual results of the adsorption process and the process could kinetically explained by the pseudo-second-order equation. Thermodynamic investigation of the process showed the adsorption of methyl orange was exothermic and spontaneous. The results revealed that MgFe2O4 sample (qmax = 181.34 mg/g) can be suggested as a good adsorbent for the removal of toxic dyes and water pollutants.
https://www.jwent.net/article_40553_d194f3cdfe5a7a4ef4d30768f79d5ced.pdf
2020-01-01
1
16
10.22090/jwent.2020.01.001
Mg-Fe Spinel
Fe3O4
Magnetic Particles
Adsorption
Methyl Orange (MO)
Behgam
Rahmanivahid
behgam@esfaraye.ac.ir
1
Department of Chemical Engineering, Esfarayen University of Technology, Esfarayen, North Khorasan, Iran
AUTHOR
Freshteh
Naderi
fnaderi@qodsiau.ac.ir
2
Department of Chemistry, Shahr-e-Qods Branch, Islamic Azad University, Tehran, Iran
AUTHOR
Hamed
Nayebzadeh
h.nayebzadeh@yahoo.com
3
Department of Chemical Engineering, Esfarayen University of Technology, Esfarayen, North Khorasan, Iran
LEAD_AUTHOR
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ORIGINAL_ARTICLE
Poly(O-Toluidine)/Zirconium-based nanocomposite ion-exchangers for Water treatment and environmental remediation
A three component nanocomposite Poly(O-Toluidine) Zr(IV) based ion exchangers are synthesized by sol-gel method and characterized by Fourier transform-infrared spectra, , X-ray diffraction, scanning electron microscopy, thermo gravimetric analysis, ion exchange studies, conductivity and antimicrobial studies. The organic polymeric part of the composites provides mechanical and chemical stability whereas the inorganic part supports the ion-exchange behavior, thermal stability and also increases the electrical conductivity due to the good ion-exchange behavior of Zirconium (IV) molybdophosphate and Zirconium(IV) iodovanadate . The nano composite of POT/ Zr(IV) Zirconium(IV) iodovanadate exhibited an excellent ion exchange capacity value for Na+ is 4.84 meq g −1 and POT/Zr(IV) molybdo phosphate ion-exchanger has the value 4.60 meq/g . While compared to other nanocomposite ion-exchangers both the ion–exchangers have significant and effective ion-exchange behaviour . From the sorption studies and the distribution coefficient values , both the composite ion exchangers show maximum selectivity towards Pb2+.They can conjugate the mechanical properties of the organic polymers with intrinsic properties of the inorganic ion exchangers creating a new class of hybrid organic – inorganic materials with improvement in thermal stability and good electrical conductivity, ion – exchange capacity and also showed higher antimicrobial activity against Gram positive and Gram negative bacteria like Escherchia coli, Pseudomonas and Staphylococcus saprophitocus, which leads to their usage for environmental remediation like water purification.POT/Zr(IV) molybdophosphate and POT/Zr(IV) iodovanadate nanocomposite ion exchangers were used as promising ion exchangers and applied as electrochemically switchable ion exchanger for water treatment, especially water softening
https://www.jwent.net/article_40554_7b02edc864fe4e7867d321a33289843a.pdf
2020-01-01
17
33
10.22090/jwent.2020.01.002
Zr(IV)molybdo phosphate
Zr(IV) iodovanadate
Conducting nanocomposites
Cation-exchanger
Sol-gel Method
Jacinth Mispa
Kanagaraj
mispajacinth@yahoo.com
1
Department of Chemistry, Aditanar College of Arts and Science, Tiruchendur-628 216, Tamilnadu, India
LEAD_AUTHOR
Regini
Chelladurai
regini1987@gmail.com
2
Department of Chemistry, Aditanar College of Arts and Science, Tiruchendur-628 216, Tamilnadu, India
AUTHOR
Subramaniam
Perumal
subramaniam.perumal@gmail.com
3
Manonmaniam Sundaranar University, Abishekapatti, Tirunelveli 627 012, Tamilnadu, India
AUTHOR
Murugesan
Rajamani
rmuru2006@yahoo.co.in
4
Department of Chemistry, T.D.M.N.S. College, T. Kallikulam-627113, Tamilnadu, India
AUTHOR
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62
ORIGINAL_ARTICLE
Trinitroanisole Adsorption on the Surface of Boron Nitride Nanocluster (B12N12): A Computational Study
This paper investigated boron nitride nanocage performance as an adsorbent and sensing material for removal and detection of trinitroanisole by density functional theory. The calculated adsorption energies, Gibbs free energy changes (ΔGad), adsorption enthalpy changes (ΔHad) and thermodynamic equilibrium constants (Kth) revealed the adsorption process is experimentally feasible, spontaneous, exothermic and Irreversible. The highly negative adsorption energy values and bond lengths between B12N12 and trinitroanisole indicated the interaction between the adsorbate and the adsorbent is a chemisorption process. The N-O and C-N bond lengths and the density values showed that trinitroanisole complexes with boron nitride cage have higher explosive velocity and detonation pressure than the pure trinitroanisole without B12N12. The frontier molecular orbital parameters such as band gap, chemical hardness, electrophilicity, chemical potential and charge capacity were also studied and the findings proved B12N12 is an excellent sensing material for fabricating novel electrochemical and thermal sensors for detection of trinitroanisole.
https://www.jwent.net/article_40555_0c44dae3845d2aa5cb0ef0d89749f0db.pdf
2020-01-01
34
44
10.22090/jwent.2020.01.003
Nitroaromatic explosives
DFT
Adsorption
Boron nitride cage
Detection
Mohammad Reza
Jalali Sarvestani
rezajalali93@yahoo.com
1
Young Researchers and Elite Club, Yadegar-e-Imam Khomeini(RAH) Shahr-e-Rey Branch, Islamic Azad University, Tehran, Iran
AUTHOR
Roya
Ahmadi
roya.ahmadi.chem@hotmail.com
2
Department of Chemistry, Yadegar-e-Imam Khomeini (RAH) Shahre-rey Branch, Islamic Azad University, Tehran, Iran
LEAD_AUTHOR
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ORIGINAL_ARTICLE
Decomposition of petroleum contaminants (naphthol) by ultraviolet (UV) radiation using a green-synthetized titanium dioxide (TiO₂) catalyst
A simple and eco-friendly method for synthesis nanoparticles is using a green chemistry technique. Also, the utilization of green nanoparticles for the treatment of industrial wastewater could be an outstanding plan to confront environmental pollutions. The novelty of this study was to use leaf extract of Stevia Rebaudiana Bertoni for green synthesized TiO₂ NPs and assessing its functioning for the photocatalytic treatment of Naphthol from real sample wastewater in a self-designed photoreactor. The amount of nano-adsorbent changes was studied under different conditions such as the amount of naphthol concentration, pH, and time period of degradation. Results: The results of the XRD showed that the Anatase and Rutile phase of TiO₂ conformed to cards no.JCPDS21-1272 and no.JCPDS21-1276 respectively. The EDX analysis illustrated the existence of TiO₂ with a weight percentage of 50.17 wt.% for Ti and 49/83 for O. The size of the particles in the SEM photo was found to be about 17nm. The removal of naphthol content was measured by the UV-Vis method. The optimum pH for naphthol removal by TiO₂ is pH = 9, the optimal contact time is 20 min, and the optimal concentration of Naphthol is 3 mg/L. Comparing the Freundlich and Langmuir adsorption isotherm models revealed that the absorption model in this study is in complete conformity with the Freundlich adsorption model. This study affirms that the green synthesis of Stevia leaf extracted is a modern beneficial procedure for the preparation of TiO₂ nanoparticles. This method is straightforward, cost-effective, eco-friendly, and rapid.
https://www.jwent.net/article_40556_266bd52a4c1e5193fb8027446fe7c3e0.pdf
2020-01-01
45
55
10.22090/jwent.2020.01.004
Photocatalytic degradation
Organic contaminants
Green synthesis
Nano-titanium dioxide (TiO₂)
Pantea
Arjmandi
panteaarjmandi@gmail.com
1
Department of Environmental Science, Faculty of Natrual Resources and Environment, Science and Research branch, Islamic Azad University, Tehran, Iran
LEAD_AUTHOR
Fariba
Hargalani
zamani.fariba@gmail.com
2
Department of Environmental Science, Faculty of Natrual Resources and Environment, Science and Research branch, Islamic Azad University, Tehran, Iran
AUTHOR
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12. Iliev V, Tomova D, Bilyarska L. Promoting the oxidative removal rate of 2,4-dichlorophenoxyacetic acid on gold-doped WO3/TiO2/reduced graphene oxide photocatalysts under UV light irradiation. Journal of Photochemistry and Photobiology A: Chemistry. 2018;351:69-77.
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15. K. Ganapathirao, D. Chinthakuntla, K. Rao, C. Chakra and P. Tambur, “Green Synthesis of TiO2 Nanoparticles Using Aloe Vera Extract,” International Journal of Advanced Research in Physical Science , vol. 2, no. 1A, pp. 28-35, 2015.
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18. Sethy NK, Arif Z, Mishra PK, Kumar P. Green synthesis of TiO2 nanoparticles from Syzygium cumini extract for photo-catalytic removal of lead (Pb) in explosive industrial wastewater. Green Processing and Synthesis. 2020;9(1):171-81.
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19. Prathyusha Kantheti and Padma Alapati, “Green synthesis of TIO2 nanoparticles using,” International Journal of Chemical Studies, vol. 6, no. 4, 2018.
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20. Subhapriya S, Gomathipriya P. Green synthesis of titanium dioxide (TiO2) nanoparticles by Trigonella foenum-graecum extract and its antimicrobial properties. Microbial Pathogenesis. 2018;116:215-20.
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22. Nabi G, Raza W, Tahir MB. Green Synthesis of TiO2 Nanoparticle Using Cinnamon Powder Extract and the Study of Optical Properties. Journal of Inorganic and Organometallic Polymers and Materials. 2019;30(4):1425-9.
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23. Foster SL, Estoque K, Voecks M, Rentz N, Greenlee LF. Removal of Synthetic Azo Dye Using Bimetallic Nickel-Iron Nanoparticles. Journal of Nanomaterials. 2019;2019:1-12.
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24. E. Talat Helmy, A. El Nemr, M. Mousa, E. Arafa and S. Eldafrawy, “Photocatalytic degradation of organic dyes pollutants in the industrial textile wastewater by using synthesized TiO2, C-doped TiO2, S-doped TiO2 and C,S co-doped TiO2 nanoparticles,” Journal of Water and Environment Nanothennology, vol. 3, no. 2, pp. 116-127, 2018.
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38. B. Rezaei and H. Mosaddeghi, “Applications of Titanium Dioxide Nanoparticles,” in Nano-Technology in Environments Conference, Isfahan, 2009.
37
ORIGINAL_ARTICLE
Removal of bisphenol A from water solution using molecularly imprinted nanopolymers: isotherm and kinetic studies
In the present study, adsorption behavior of mesoporous molecularly imprinted polymers for bisphenol A was investigated. Molecularly imprinted nanopolymers were synthesized by precipitation polymerization using bisphenol A as a template molecule. Two molecular ratios of templet: functional monomer: cross-linker (1:6:30 (MIP-6) and 1:4:20 (MIP-4)) was considered for experiments. Ethylene Glycol Dimethacrylate (EGDMA) as a Crosslinker, metacrylic acid (MAA) as a functional monomer and 2, 2´-azobisisobutyronitrile (AIBN) as an initiator were used for the synthesis of polymers. In addition, Langmuir and Freundlich adsorption isotherms and pseudo-first-order and pseudo-second-order kinetic models were studied for adsorption mechanism. Results showed that porous polymers with average pore diameter of 13 to 17 nm and specific surface area of 326 to 439 (cm3/g) were obtained. The maximum adsorption capacity was 400.1 μmol/g for MIP-6. SEM analysis showed that the synthesized polymer particles were spherical. The highest adsorption efficiency of bisphenol A achieved by MIP-6 was 71%.
https://www.jwent.net/article_40557_7d68142f87194915eee0cfe808f02bd5.pdf
2020-01-01
56
67
10.22090/jwent.2020.01.005
Bisphenol A
Molecularly imprinted polymer
Mesosphere
Isotherm
Kinetic adsorption
Seyedeh Maedeh
Hashemi Orimi
maedeh_31@yahoo.com
1
Department of Chemical Engineering, Ayatollah Amoli Branch, Islamic Azad University, Amol, Iran
AUTHOR
Maryam
Khavarpour
mkhavarpoor@yahoo.com
2
Department of Chemical Engineering, Ayatollah Amoli Branch, Islamic Azad University, Amol, Iran
LEAD_AUTHOR
Sohrab
Kazemi
kazemi.msm@gmail.com
3
Cellular and Molecular Biology Research Center, Babol University of Medical Sciences, Babol, Iran
AUTHOR
1. Zhou H, Xu Y, Tong H, Liu Y, Han F, Yan X, et al. Direct synthesis of surface molecularly imprinted polymers based on vinyl-SiO2nanospheres for recognition of bisphenol A. Journal of Applied Polymer Science. 2012;128(6):3846-52.
1
2. Yin J, Meng Z, Zhu Y, Song M, Wang H. Dummy molecularly imprinted polymer for selective screening of trace bisphenols in river water. Anal Methods. 2011;3(1):173-80.
2
3. Yan H, Liu S, Gao M, Sun N. Ionic liquids modified dummy molecularly imprinted microspheres as solid phase extraction materials for the determination of clenbuterol and clorprenaline in urine. Journal of Chromatography A. 2013;1294:10-6.
3
4. Curcio P, Zandanel C, Wagner A, Mioskowski C, Baati R. Semi-Covalent Surface Molecular Imprinting of Polymers by One-Stage Mini-emulsion Polymerization: Glucopyranoside as a Model Analyte. Macromolecular Bioscience. 2009;9(6):596-604.
4
5. Wang Y, Liu Q, Rong F, Fu D. A facile method for grafting of bisphenol A imprinted polymer shells onto poly(divinylbenzene) microspheres through precipitation polymerization. Applied Surface Science. 2011;257(15):6704-10.
5
6. Luliński P, Dana M, Maciejewska D. Synthesis and characterization of 3,4-dihydroxyphenylacetic acid imprin-ted polymers. Polymer International. 2011;61(4):631-8.
6
7. Abouzarzadeh A, Forouzani M, Jahanshahi M, Bahramifar N. Synthesis and evaluation of uniformly sized nalidixic acid-imprinted nanospheres based on precipitation polymerization method for analytical and biomedical applications. Journal of Molecular Recognition. 2012;25(7):404-13.
7
8. Yoshimatsu K, Yamazaki T, Chronakis IS, Ye L. Influence of template/functional monomer/cross-linking monomer ratio on particle size and binding properties of molecularly imprinted nanoparticles. Journal of Applied Polymer Science. 2011;124(2):1249-55.
8
9. Beyki T, Asadollahzadeh MJ. Selective removal of dicamba from aqueous samples using molecularly imprinted polymer nanospheres. J. Water Environ. Nanotechnol. 2016;1(1):19-25.
9
10. Yoshimatsu K, Reimhult K, Krozer A, Mosbach K, Sode K, Ye L. Corrigendum to “Uniform molecularly imprinted microspheres and nanoparticles prepared by precipitation polymerization: The control of particle size suitable for different analytical applications” [Anal. Chim. Acta 584 (2007) 112–121]. Analytica Chimica Acta. 2010;657(2):215.
10
11. Refaat D, Aggour MG, Farghali AA, Mahajan R, Wiklander JG, Nicholls IA, et al. Strategies for Molecular Imprinting and the Evolution of MIP Nanoparticles as Plastic Antibodies—Synthesis and Applications. International Journal of Molecular Sciences. 2019;20(24):6304.
11
12. Soleimani M, Ghaderi S, Afshar MG, Soleimani S. Synthesis of molecularly imprinted polymer as a sorbent for solid phase extraction of bovine albumin from whey, milk, urine and serum. Microchemical Journal. 2012;100:1-7.
12
13. Maragou NC, Thomaidis NS, Theodoridis GA, Lampi EN, Koupparis MA. Determination of bisphenol A in canned food by microwave assisted extraction, molecularly imprinted polymer-solid phase extraction and liquid chromatography-mass spectrometry. Journal of Chromatography B. 2020;1137:121938.
13
14. Moreira FTC, Sales MGF. Biomimetic sensors of molecularly-imprinted polymers for chlorpromazine determination. Materials Science and Engineering: C. 2011;31(5):1121-8.
14
15. Alenazi N, Manthorpe J, Lai E. Selectivity Enhancement in Molecularly Imprinted Polymers for Binding of Bisphenol A. Sensors. 2016;16(10):1697.
15
16. Yuan Y, Liu Y, Teng W, Tan J, Liang Y, Tang Y. Preparation of core-shell magnetic molecular imprinted polymer with binary monomer for the fast and selective extraction of bisphenol A from milk. Journal of Chromatography A. 2016;1462:2-7.
16
17. Zaidi SA. Molecular imprinting: A useful approach for drug delivery. Materials Science for Energy Technologies. 2020;3:72-7.
17
18. Tarannum N, Hendrickson OD, Khatoon S, Zherdev AV, Dzantiev BB. Molecularly imprinted polymers as receptors for assays of antibiotics. Critical Reviews in Analytical Chemistry. 2019:1-20.
18
19. Jurek A, Leitner E. Analytical determination of bisphenol A (BPA) and bisphenol analogues in paper products by LC-MS/MS. Food Additives & Contaminants: Part A. 2018;35(11):2256-69.
19
20. Zhang J, Li X, Zhou L, Wang L, Zhou Q, Huang X. Analysis of effects of a new environmental pollutant, bisphenol A, on antioxidant systems in soybean roots at different growth stages. Scientific Reports. 2016;6(1).
20
21. Caballero-Casero N, Lunar L, Rubio S. Analytical methods for the determination of mixtures of bisphenols and derivatives in human and environmental exposure sources and biological fluids. A review. Analytica Chimica Acta. 2016;908:22-53.
21
22. Huang YQ, Wong CKC, Zheng JS, Bouwman H, Barra R, Wahlström B, et al. Bisphenol A (BPA) in China: A review of sources, environmental levels, and potential human health impacts. Environment International. 2012;42:91-9.
22
23. Park C, Song H, Choi J, Sim S, Kojima H, Park J, et al. The mixture effects of bisphenol derivatives on estrogen receptor and androgen receptor. Environmental Pollution. 2020;260:114036.
23
24. Hiratsuka Y, Funaya N, Matsunaga H, Haginaka J. Preparation of magnetic molecularly imprinted polymers for bisphenol A and its analogues and their application to the assay of bisphenol A in river water. Journal of Pharmaceutical and Biomedical Analysis. 2013;75:180-5.
24
25. Alexiadou DK, Maragou NC, Thomaidis NS, Theodoridis GA, Koupparis MA. Molecularly imprinted polymers for bisphenol A for HPLC and SPE from water and milk. Journal of Separation Science. 2008;31(12):2272-82.
25
26. Karaman Ersoy Ş, Tütem E, Sözgen Başkan K, Apak R, Nergiz C. Preparation, characterization and usage of molecularly imprinted polymer for the isolation of quercetin from hydrolyzed nettle extract. Journal of Chromatography B. 2016;1017-1018:89-100.
26
27. Sun X, Wang J, Li Y, Jin J, Zhang B, Shah SM, et al. Highly selective dummy molecularly imprinted polymer as a solid-phase extraction sorbent for five bisphenols in tap and river water. Journal of Chromatography A. 2014;1343:33-41.
27
28. Langmuir I. THE ADSORPTION OF GASES ON PLANE SURFACES OF GLASS, MICA AND PLATINUM. Journal of the American Chemical Society. 1918;40(9):1361-403.
28
29. Scatchard G. THE ATTRACTIONS OF PROTEINS FOR SMALL MOLECULES AND IONS. Annals of the New York Academy of Sciences. 1949;51(4):660-72.
29
30. Bayramoglu G, Arica MY, Liman G, Celikbicak O, Salih B. Removal of bisphenol A from aqueous medium using molecularly surface imprinted microbeads. Chemosphere. 2016;150:275-84.
30
ORIGINAL_ARTICLE
Optimization of copper adsorption process from aqueous solution by Descurainia sophia plant stem using Taguchi method
The aim of this project is the production of The Descurainia Sophia adsorbent in nano dimensions using a super-grinding disk mill. The top-down method was used in the process of nanogel preparation. After complete drying of the stems, the stems were reduced to smaller sizes by an electric mill, and by using the available sieve to standard number 60, adsorbent granulation was performed. The adsorbent was used to remove copper from aqueous solution. The tests and their optimization results were based on the design of experiments in three levels of variables using Taguchi method. According to the experiment results, pH, contact time, and adsorption mass are the main factors and the most influential effect on the removal of copper from the aqueous solution is the pH parameter, which has a lower p-value. As the pH increases from 5 to 9, the efficiency of copper metal removal increases. The concentration of hydrogen ions is the most important parameter affecting the adsorption process. The effect of temperature on adsorption efficiency has been investigated in the range of 20-50°C. Finally, the highest efficiency of copper cation removal was at 30°C and 8.89%. The results showed that the pH of the solution had the most effect on the copper removal efficiency and in the playing environment, the effect of copper removal was more than the acid and neutral conditions of the solution. Also, the adsorbent mass and contact time have the most effect on copper removal after the pH parameter in the Taguchi method.
https://www.jwent.net/article_40558_b6b5fc7677999aa06767565feff7e33b.pdf
2020-01-01
68
80
10.22090/jwent.2020.01.006
Nanogel
Descurainia sophia Plant Stem
Design of Experiments (DoE)
Taguchi method
kimia
yadolahi
yadolahi.kimia@gmail.com
1
Department of Chemical Engineering, Science and research branch, Islamic Azad University, Tehran, Iran.
AUTHOR
Arezoo
Ghadi
arezoo.ghadi@gmail.com
2
Department of Chemical Engineering, Islamic Azad University, Ayatollah Amoli Branch, Amol, Iran.
LEAD_AUTHOR
Seyed Abolhasan
Alavi
alavi.ab@gmail.com
3
Department of Chemical Engineering, Science and research branch, Islamic Azad University, Tehran, Iran.
AUTHOR
1. Gupta VK, Suhas. Application of low-cost adsorbents for dye removal – A review. Journal of Environmental Management. 2009;90(8):2313-42.
1
2. Ji G, Bao W, Gao G, An B, Zou H, Gan S. Removal of Cu (II) from Aqueous Solution Using a Novel Crosslinked Alumina-Chitosan Hybrid Adsorbent. Chinese Journal of Chemical Engineering. 2012;20(4):641-8.
2
3. Sivasankar V, Rajkumar S, Murugesh S, Darchen A. Tamarind (Tamarindus indica) fruit shell carbon: A calcium-rich promising adsorbent for fluoride removal from groundwater. Journal of Hazardous Materials. 2012;225-226:164-72.
3
4. Visa M. Tailoring fly ash activated with bentonite as adsorbent for complex wastewater treatment. Applied Surface Science. 2012;263:753-62.
4
5. Sánchez-Martín J, Beltrán-Heredia J, Gragera-Carvajal J. Caesalpinia spinosa and Castanea sativa tannins: A new source of biopolymers with adsorbent capacity. Preliminary assessment on cationic dye removal. Industrial Crops and Products. 2011;34(1):1238-40.
5
6. Dawood S, Sen TK. Removal of anionic dye Congo red from aqueous solution by raw pine and acid-treated pine cone powder as adsorbent: Equilibrium, thermodynamic, kinetics, mechanism and process design. Water Research. 2012;46(6):1933-46.
6
7. Hong S, Candelone JP, Patterson CC, Boutron CF. History of Ancient Copper Smelting Pollution During Roman and Medieval Times Recorded in Greenland Ice. Science. 1996;272(5259):246-9.
7
8. Kurczewska J, Schroeder G, Narkiewicz U. Copper removal by carbon nanomaterials bearing cyclam-functionalized silica. Open Chemistry. 2010;8(2).
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9. Moralı U, Demiral H, Şensöz S. Optimization of activated carbon production from sunflower seed extracted meal: Taguchi design of experiment approach and analysis of variance. Journal of Cleaner Production. 2018;189:602-11.
9
10. Googerdchian F, Moheb A, Emadi R, Asgari M. Optimization of Pb(II) ions adsorption on nanohydroxyapatite adsorbents by applying Taguchi method. Journal of Hazardous Materials. 2018;349:186-94.
10
11. Okuno D, Iwase T, Shinzawa-Itoh K, Yoshikawa S, Kitagawa T. FTIR Detection of Protonation/Deprotonation of Key Carboxyl Side Chains Caused by Redox Change of the CuA-HemeaMoiety and Ligand Dissociation from the Hemea3-CuBCenter of Bovine Heart CytochromecOxidase. Journal of the American Chemical Society. 2003;125(24):7209-18.
11
12. Hadjiivanov K, Lamotte J, Lavalley J-C. FTIR Study of Low-Temperature CO Adsorption on Pure and Ammonia-Precovered TiO2(Anatase). Langmuir. 1997;13(13):3374-81.
12
13. Mendelovici E, Frost RL, Kloprogge JT. Modification of Chrysotile Surface by Organosilanes: An IR–Photoacoustic Spectroscopy Study. Journal of Colloid and Interface Science. 2001;238(2):273-8.
13
14. van Thor JJ, Fisher N, Rich PR. Assignments of the Pfr−Pr FTIR Difference Spectrum of Cyanobacterial Phytochrome Cph1 Using15N and13C Isotopically Labeled Phycocyanobilin Chromophore. The Journal of Physical Chemistry B. 2005;109(43):20597-604.
14
15. Edrissi M, Norouzbeigi R. Taguchi Optimization for Combustion Synthesis of Aluminum Oxide Nano-particles. Chinese Journal of Chemistry. 2008;26(8):1401-6.
15
16. Das AK, Saha S, Pal A, Maji SK. Surfactant-modified alumina: An efficient adsorbent for malachite green removal from water environment. Journal of Environmental Science and Health, Part A. 2009;44(9):896-905.
16
17. Wang CM, Wu H, Chung SL. Optimization of experimental conditions based on Taguchi robust design for the preparation of nano-sized TiO2 particles by solution combustion method. Journal of Porous Materials. 2006;13(3-4):307-14.
17
18. Roy, R.K., Design of experiments using the Taguchi approach: 16 steps to product and process improvement. 2001: John Wiley & Sons.
18
19. Ghodbane I, Hamdaoui O. Removal of mercury(II) from aqueous media using eucalyptus bark: Kinetic and equilibrium studies. Journal of Hazardous Materials. 2008;160(2-3):301-9.
19
20. Azman, H., Bioligninolysis: degradation of ionic liquid derived lignin by Rhodococcus. 2015.
20
ORIGINAL_ARTICLE
Green Synthesis and Characterization of Silver Nano Particles
Nanotechnology is getting an incredible drive due to the potential of manipulating metals into their nano size particles. The synthesis and characterization of nano particles using green technology have many applications. The wet chemical techniques used presently in the synthesis of nano particles are deleterious along with flammable conditions. Silver nanoparticles have the capability of killing microbes in an effective manner. This paper explains about the green technology and pollution free methodology for synthesizing silver particles at nano scale using 1mM silver nitrate solution from the extracts of Carica papaya, Emblica officianalis, Azadirachta indica and Cocos nucifera. When the silver nanoparticles are synthesized the solution turns to brownish yellow colour. The tools used in the characterisation of silver nano particles are Ultra Violet - Visible absorption Spectroscopy and Field Emission Scanning Electron Microscopy. The solutions with silver nanoparticles showed the maximum absorption at 450 nm with Ultra Violet - Visible spectroscopy. It is found that C. Papaya and E. oficianalis showed the maximum absorbance of 0.578 and 0.59 respectively at 450 nm. The average range of the produced silver nano particles are analysed to be 5 – 70 nm with FESEM and the shape is examined to be spherical.
https://www.jwent.net/article_40559_33f154df0436220f67ed6d8d1a704bf8.pdf
2020-01-01
81
91
10.22090/jwent.2020.01.007
Characterization
Green technology
Metal
Nanotechnology
Silver nanoparticles
Susarla
Sastry
svarsastry@yahoo.com
1
Department of Chemical Engineering, MVGR College of Engineering (A), Vizianagaram, Andhra Pradesh - 535005, India
LEAD_AUTHOR
1. Jain DH, Kumar Daima S., Kachhwaha SL. and Kothari, 2009. Synthesis of plant-mediated silver nanoparticles using papaya fruit extract and evaluation of their antimicrobial activities. Digest Journal of Nanomaterials and Biostructures, 4(3): 557 – 563.
1
2. Sastry SVAR, Sreenu P. Applications of nanotechnology in the field of environment. 2012 IEEE International Conference on Engineering Education: Innovative Practices and Future Trends (AICERA); 2012/07: IEEE; 2012.
2
3.Elechiguerra JL., Justin L Burt., Jose R Morones., Alejandra Camacho-Bragado., Xiaoxia Gao., Humberto H Lara and Miguel Jose Yacaman, 2005. Interaction of Silver Nanoparticles with HIV-1. Journal of Nano Biotechnology, 3(6): doi:10.1186/1477-3155-3-6.
3
4.Mritunjai Singh., Shinjini Singh., Prasada S., and Gambhir I.S., 2008. Nanotechnology in medicine and antibacterial effect of silver nanoparticles. Digest Journal of Nanomaterials and Biostructures, 3(3): 115 – 122.
4
5.Parashara U.K., Preeti S. Saxenaa., and Anchal Srivastava, 2009. Bioinspired synthesis of silver nanoparticles. Digest Journal of Nanomaterials and Biostructures, 4(1): 159 – 166.
5
6. Khan Z, Hussain JI, Hashmi AA, Al-Thabaiti SA. Preparation and characterization of silver nanoparticles using aniline. Arabian Journal of Chemistry. 2017;10:S1506-S11.
6
7.Sheikh Jaber Nurani, Chandan Kumar Saha, Md. Arifur Rahman Khan, and Sharif Masnad Hossain Sunny, 2015. Silver Nanoparticle Synthesis, Properties, Applications and Future Perspectives: A short review. Journal of Electrical and Electronics Engineering, 10(6): 117 – 126.
7
8. Anandan K, Rajendran V. Morphological and size effects of NiO nanoparticles via solvothermal process and their optical properties. Materials Science in Semiconductor Processing. 2011;14(1):43-7.
8
9. Laokul P, Amornkitbamrung V, Seraphin S, Maensiri S. Characterization and magnetic properties of nanocrystalline CuFe2O4, NiFe2O4, ZnFe2O4 powders prepared by the Aloe vera extract solution. Current Applied Physics. 2011;11(1):101-8.
9
10.Sastry M., Ahmad A., Khan MI., and Kumar R., 2009. Biosynthesis of Metal Nanoparticles Using Fungi and Actinomycete. Current Science, 85: 162-170.
10
11. Saifuddin N, Wong CW, Yasumira AAN. Rapid Biosynthesis of Silver Nanoparticles Using Culture Supernatant of Bacteria with Microwave Irradiation. E-Journal of Chemistry. 2009;6(1):61-70.
11
12. Ahmad N, Sharma S, Singh VN, Shamsi SF, Fatma A, Mehta BR. Biosynthesis of Silver Nanoparticles from Desmodium triflorum: A Novel Approach Towards Weed Utilization. Biotechnology Research International. 2011;2011:1-8.
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13. Philip D. Green synthesis of gold and silver nanoparticles using Hibiscus rosa sinensis. Physica E: Low-dimensional Systems and Nanostructures. 2010;42(5):1417-24.
13
14. Philip D, Unni C, Aromal SA, Vidhu VK. Murraya Koenigii leaf-assisted rapid green synthesis of silver and gold nanoparticles. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2011;78(2):899-904.
14
15.Padma S Vankar and Dhara Bajpai, 2010. Preparation of Gold nanoparticles from Mirabilis jalapa flowers. Indian Journal of Biochemistry & Biophysics, 47: 157-160.
15
16.Safaepour M., Ahmed Reza Shahverdi., Hamid Reza Shahverdi., Mohammad Reza Kharramizadeh., and Ahmed Reza Gohari., 2009. Green synthesis of small silver nanoparticles using Geraniol and its cytotoxicity against Fibrosarcoma - Wehi 164. Avicenna Journal of Medical Biotechnology, 1(2): 111–115.
16
17.Guzmán M.G., Jean Dille., and Stephan Godet, 2008. Synthesis of Silver Nanoparticles by chemical reduction method and their antibacterial activity. International Journal of Materials and Metallurgical Engineering, 2(7): 91 – 98.
17
18. Lee S, Jun B-H. Silver Nanoparticles: Synthesis and Application for Nanomedicine. International Journal of Molecular Sciences. 2019;20(4):865.
18
19. Pirtarighat S, Ghannadnia M, Baghshahi S. Green synthesis of silver nanoparticles using the plant extract of Salvia spinosa grown in vitro and their antibacterial activity assessment. Journal of Nanostructure in Chemistry. 2018;9(1):1-9.
19
20. Goorani S, Shariatifar N, Seydi N, Zangeneh A, Moradi R, Tari B, et al. The aqueous extract of Allium saralicum R.M. Fritsch effectively treat induced anemia: experimental study on Wistar rats. Oriental Pharmacy and Experimental Medicine. 2019;19(4):403-13.
20
21. Moradi R, Hajialiani M, Salmani S, Almasi M, Zangeneh A, Zangeneh MM. Effect of aqueous extract of Allium saralicum R.M. Fritsch on fatty liver induced by high-fat diet in Wistar rats. Comparative Clinical Pathology. 2018;28(5):1205-11.
21
22. Zangeneh MM, Bovandi S, Gharehyakheh S, Zangeneh A, Irani P. Green synthesis and chemical characterization of silver nanoparticles obtained using Allium saralicum aqueous extract and survey of in vitro antioxidant, cytotoxic, antibacterial and antifungal properties. Applied Organometallic Chemistry. 2019;33(7).
22
23. Zangeneh MM, Ghaneialvar H, Akbaribazm M, Ghanimatdan M, Abbasi N, Goorani S, et al. Novel synthesis of Falcaria vulgaris leaf extract conjugated copper nanoparticles with potent cytotoxicity, antioxidant, antifungal, antibacterial, and cutaneous wound healing activities under in vitro and in vivo condition. Journal of Photochemistry and Photobiology B: Biology. 2019;197:111556.
23
24. Arsiya F, Sayadi MH, Sobhani S. Green synthesis of palladium nanoparticles using Chlorella vulgaris. Materials Letters. 2017;186:113-5.
24
25. Sayadi MH, Salmani N, Heidari A, Rezaei MR. Bio-synthesis of palladium nanoparticle using Spirulina platensis alga extract and its application as adsorbent. Surfaces and Interfaces. 2018;10:136-43.
25
26.Hadeel Jawad, Al Houri, Nadine M.S., Moubayed and Sumia Ibrahim Irsan, 2015. Silver nanoparticles biosynthesis using Spirulina platensis used as antioxidant and antimicrobial agent. Pharm Lett, 7(2): 9-21.
26
27. Karimi, Javanshir, Sayadi, Arabyarmohammadi. Arsenic Removal from Mining Effluents Using Plant-Mediated, Green-Synthesized Iron Nanoparticles. Processes. 2019;7(10):759.
27
28. Oves M, Aslam M, Rauf MA, Qayyum S, Qari HA, Khan MS, et al. Antimicrobial and anticancer activities of silver nanoparticles synthesized from the root hair extract of Phoenix dactylifera. Materials Science and Engineering: C. 2018;89:429-43.
28
ORIGINAL_ARTICLE
Assessment of Water Quality Status and Zooplanktons of River Bhagirathi In Uttarkashi
The present paper was depicted to analyze the water quality status in single terms and zooplanktons of the Bhagirathi river. The water quality parameters were analyzed in lab.such as pH, Total Dissolved Solid (TDS), Total Hardness (TH), Chloride, Dissolved Oxygen, Calcium , Biochemical Oxygen Demand (BOD and Chloride. In the I site of the first area , the value of WQI in monsoon 55.79, winter 31.73 and summer 45.66, In the site 2, the value of WQI in monsoon 61.46 ,winter 38.17and summer 46.42 , In the site 3 ,the value of WQI in monsoon 61.36 , winter 32.91 and summer 47.55 were observed. Water quality index in the all study site is good in winter and summer, but poor in monsoon season. These fresh water systems also support various forms of aquatic life. The zooplankton of our study site mainly comprised of Protozoa, Rotifer, Copepoda and Cladocera. A total of 11 genera of Zooplanktons were observed during the course of study. The maximum number of Zooplanktons genera was during winter and minimum during rainy season. The most remarkable aspect of River Bhagirathi at these sites seems to be the tremendous potential to heal the health of entire river ecology that get damaged due to insufficient water released from the hydro-electric power project after dam wall into the main river channel .Immediate steps need to be taken in order to restore the ecological balance – mainly in main river channels after the dam wall of hydro-electric power projects.
https://www.jwent.net/article_40560_e10cc3027ef13a57d884f60f16d4b66b.pdf
2020-01-01
92
101
10.22090/jwent.2020.01.008
Water quality Status
Water Quality Index
Physico-chemical parameters
Bio-indicators” of an aquatic ecosystems
Mahidhar Prasad
Tiwari
mptiwari90@gmail.com
1
Department of Chemistry, Govt PG College Uttakashi,Uttrakhand, India
LEAD_AUTHOR
Poonam
Tiwari
pntiwarit@gmail.com
2
Department of Zoology Govt PG College Uttakashi, Uttrakhand, India
AUTHOR
1. Tiwari AK, Singh AK. Hydrogeochemical investigation and groundwater quality assessment of Pratapgarh district, Uttar Pradesh. Journal of the Geological Society of India. 2014;83(3):329-43.
1
2.Sinha, U.K. Ganga River Pollutions and health Hazard, Inter-India Publication, New Delhi.1986.
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3.Abbasi SA Water quality indices. Elsevier, Amsterdam,2002.
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4. Samantray P, Mishra BK, Panda CR, Rout SP. Assessment of Water Quality Index in Mahanadi and Atharabanki Rivers and Taldanda Canal in Paradip Area, India. Journal of Human Ecology. 2009;26(3):153-61.
4
5.Laishram, K Pollution status and conservation strategies of Moirange river, Manipur with a note on its aquatic bio-resource. Journal of Environmental Biology, 2007; 28(3): 669-673.
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6.Nikolsky G.V Ecology of fish. Published by Allied Scientific publisher Vyas Nagar, Bikaner India, 1999.
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7. Sládeček V. Rotifers as indicators of water quality. Hydrobiologia. 1983;100(1):169-201.
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8.Das P, Micheal R , Gupta A.. Trop. Ecol, 1996 37, 257.
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9.Kumar A, Tripathi G, Ghosh PStatus of freshwater in 21st century: A Review- in. . 2004.
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10.Nikolsky G.V;Ecology of Fishes Published by Allied Scientific Publishers, b Vyas Nagar Bikaner.India;1999.
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11.Kaushik S, Agarkar MS, Saxena DN. Distribution of phytoplankton in riverine waters in Chambal area, Madhya Pradesh. Bio nature 12, 1-7;1992.
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12.Trivedi. R.K. and Goyal P.K Chemical and biological methods for water pollution studies, Enviornment publication Karad. 1986; 248:11.
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13.APHA .Standard methods for analysis of water quality and wastewater, 21st edn. American Public Health Association, Washington. 2005.
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14.Dutta. and Munshi J.D. Fundamental of freshwater biology Publisher: U.P. Sharma Bhagalpur.1995.
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15.Brown, R. M, Water quality index – crossing the physical barrier (Jenkis, S H ed) Proc. Intl. Conf. on water pollution Res. Jerusalem.1972; 6: 787 – 797.
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16.Bureau of Indian Standards (BIS), Specification of drinking water. IS: 10500, Bureau of Indian Standards, New Delhi.2005.
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17. Kumar A, Bisht BS, Joshi VD, Singh AK, Talwar A. Physical, Chemical and Bacteriological Study of Water from Rivers of Uttarakhand. Journal of Human Ecology. 2010;32(3):169-73.
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18.Badola S.P ;Ichthyology of the central Himalaya (book) 2009.
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19.Gurumayum S.D, Daimari P, Goswami B.S, Sagar A and Choudhury M. Physico-Chemical qualities of water and planktons of selected rivers in Meghalaya. J. Inland Fisheries Soci.of India. 2000;34 :36-42.
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