ORIGINAL_ARTICLE
Phytofabrication of fluorescent silver nanoparticles from Leucaena leucocephala L. leaves and their biological activities
The aim of this study was to expand an ecofriendly route for the fabrication of spherical shape silver nanoparticles (AgNPs) using an aqueous extract of Leucaena leucocephala L. leaves to act as stabilizing and reducing agent. Several biomolecules present in plant extract are accountable for single step reduction of metal ions into nanoparticles. The synthesized AgNPs were characterized by X-ray diffraction (XRD) profile, Fourier transform infrared (FTIR) spectroscopy, field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), Energy-dispersive X-ray spectroscopy (EDS) and Photoluminescence. Besides these, AgNPs evinced potent antibacterial, antimalarial and antimycobacterial activity against Pseudomonas aeruginosa, Streptococcus pyogenes, Staphylococcus aureus, Escherichia coli, Salmonella typhi, Bacillus subtilis, Plasmodium falciparum and Mycobacterium tuberculosis. The results suggest that the efficiently synthesized AgNPs can be used as potential candidates for various medicinal applications in bionanotechnology based industries.
https://www.jwent.net/article_31132_d7b840ee6fdf212d01cf9d9ec8cec3d8.pdf
2018-04-01
95
105
10.22090/jwent.2018.02.001
AgNPs
Biological activity
Leucaena leucocephala L
Nanotechnology
Suresh
Ghotekar
ghotekarsuresh7@gmail.com
1
Department of Chemistry, KKHA Arts, SMGL Comm. and SPHJ Science College, Chandwad 423 101, Savitribai Phule Pune University, Maharashtra, India
LEAD_AUTHOR
Ajay
Savale
ajaysavle93@gmail.com
2
Department of Applied Science and Humanities, G. M. Vedak Institute of Technology, Tala, Raigad 402 111, University of Mumbai, Maharashtra, India
AUTHOR
Shreyas
Pansambal
shreyas.pansambal@gmail.com
3
Department of Chemistry, S.N. Arts, D.J.M. Comm. and B.N.S. Science College, Sangamner 422 605, Savitribai Phule Pune University, Maharashtra, India
AUTHOR
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41
ORIGINAL_ARTICLE
Plant- mediated biosynthesis of Silver nanoparticles from Gymnema sylvestre and their use in phtodegradation of Methyl orange dye
The present study reports one step green synthesis of silver nanoparticles using Gymnema sylvestre aqueous extract at room temperature and their usage in the photodegradation of methyl orange dye. The silver nanoparticles are synthesized using an aqueous extract of stem and root of Gymnema sylvestre. UV-Visible spectral analysis showed absorbance peak at 430 nm with special reference to the excitation of surfaces plasmon vibration by silver nanoparticles. FT-IR analysis of nanoparticles reveals the presence of molecular functional groups such as amides, phenolic compounds, and carboxylic acid. These phytochemicals act capping and stabilizing agents for silver nanoparticles. EDAX elemental analysis shows the presence of silver as the main element in synthesized nanoparticles. The average crystalline size of silver nanoparticles was found to be 25.3 nm and 9.97 nm for Stem-AgNPs and Root-AgNPs respectively by Scherer formula. XRD patterns also suggest the occurrence of crystalline silver ions. Further, photocatalytic degradation of methyl orange was measured spectrophotometrically by using silver nanoparticles as nanocatalyst under solar light effect. The results revealed that biosynthesized silver nanoparticles using G. sylvestyre was found to be notable in degrading methyl orange dye under the influence of sunlight.
https://www.jwent.net/article_31133_de481279f1d4b5745364b92d2c7ba9ee.pdf
2018-04-01
106
115
10.22090/jwent.2018.02.002
FTIR
Gymnema sylvestre
Photodegradation
SEM
Silver nanoparticles
Stem and Root extract
XRD
Shirish Sadashiv
Pingale
drsspingale@gmail.com
1
Department of Chemistry, ACS College Narayangaon, Junnar, Pune-410504, Maharashtra, India
LEAD_AUTHOR
Shobha Vasant
Rupanar
shobha.rupanar@gmail.com
2
Baburaoji Gholap College, New Sangavi, Pune-411027, Maharashtra, India
AUTHOR
Manohar
Chaskar
shobha.rupanar@dypic.in
3
Ramakrishna More college of Arts, Commerce and Science, Akurdi, Pune-411035, Maharashtra, India
AUTHOR
1. Nel AE, Mädler L, Velegol D, Xia T, Hoek EMV, Somasundaran P, et al. Understanding biophysicochemical interactions at the nano–bio interface. Nature Materials. 2009;8(7):543-57.
1
2. Sharma NC, Sahi SV, Nath S, Parsons JG, Gardea- Torresde JL, Pal T. Synthesis of Plant-Mediated Gold Nanoparticles and Catalytic Role of Biomatrix-Embedded Nanomaterials. Environmental Science & Technology. 2007;41(14):5137-42.
2
3. Hamed M, Givianrad M, Moradi A. Biosynthesis of Silver Nanoparticles Using Marine Sponge. Oriental Journal of Chemistry. 2015;31(4):1961-7.
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4. Kumari A, Yadav SK, Yadav SC. Biodegradable polymeric nanoparticles based drug delivery systems. Colloids and Surfaces B: Biointerfaces. 2010;75(1):1-18.
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5. Owaid MN, Ibraheem IJ. Mycosynthesis of nanoparticles using edible and medicinal mushrooms. European Journal of Nanomedicine. 2017;9(1).
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6. Bar H, Bhui DK, Sahoo GP, Sarkar P, De SP, Misra A. Green synthesis of silver nanoparticles using latex of Jatropha curcas. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2009;339(1-3):134-9.
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7. Huang J, Li Q, Sun D, Lu Y, Su Y, Yang X, et al. Biosynthesis of silver and gold nanoparticles by novel sundried Cinnamomum camphora leaf. Nanotechnology. 2007;18(10):105104.
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10. Ankamwar B, Chaudhary M, Sastry M. Gold Nanotriangles Biologically Synthesized using Tamarind Leaf Extract and Potential Application in Vapor Sensing. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 2005;35(1):19-26.
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13. Rupanar S V, S.S. Pingale, C.N. Dandge and D. Kshirsagar, 2016, Phytochemical Screening and In vitro evaluation of antioxidant & antimicrobial activity of Gymnema sylvestre, International Journal of Current Research, 8:11.
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14. Gopiesh khanna V, Kannabiran K. Antimicrobial activity of saponin fractions of the leaves of Gymnema sylvestre and Eclipta prostrata. World Journal of Microbiology and Biotechnology. 2008;24(11):2737-40.
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15. Kanetkar P, R. Singha and M. Kamat, 2007, Gymnema sylvestre: A Memoir. Journal of Clinical and Biochemistry Nutrition, 41:77-81
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18. Kumar M S, N. Astalakshmi, P. T. Arshida, K. Deepthi, N.M. Devassia, P.M .Shafna and G. Babu, 2014, A Concise Review on gurmar Gymnema sylvestre R.Br., World Journal of pharmacy and Pharmaceutical Science. 4:430-448.
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19. Muthukrishnan S, Bhakya S, Senthil Kumar T, Rao MV. Biosynthesis, characterization and antibacterial effect of plant-mediated silver nanoparticles using Ceropegia thwaitesii – An endemic species. Industrial Crops and Products. 2015;63:119-24.
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22. Kumar P, Govindaraju M, Senthamilselvi S, Premkumar K. Photocatalytic degradation of methyl orange dye using silver (Ag) nanoparticles synthesized from Ulva lactuca. Colloids and Surfaces B: Biointerfaces. 2013;103:658-61.
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24
ORIGINAL_ARTICLE
Photocatalytic degradation of organic dyes pollutants in the industrial textile wastewater by using synthesized TiO2, C-doped TiO2, S-doped TiO2 and C,S co-doped TiO2 nanoparticles
This paper describes the photocatalytic degradation of Reactive Blue 19 (RB-19) and Reactive Red 76 (RR-76) dyes pollutant in the industrial wastewater using TiO2, C-doped TiO2(C-TiO2), S-doped TiO2 (S-TiO2) and C,S co-doped TiO2 (C,S-TiO2)nanoparticles as photocatalysts, which were synthesized via sol-gel process. The prepared photocatalysts were characterized by scanning electron microscopy (SEM), X-Ray diffraction (XRD), Fourier transformer infra-red spectroscopy (FTIR), Energy dispersive spectroscopy (EDAX) and ultraviolet-visible absorption spectroscopy (UV-Vis). The dyes degradation was investigated under several experimental parameters such as pH, catalyst load, dye concentration, shaking speed, irradiation time and catalyst recovery. The photocatalytic dose was found to be 1.6 g/L and the efficiency of RB-19 and RR-76 photocatalytic degradation attained 100 % after 1 h irradiation time under visible light. The chemical oxygen demand (COD) values were determined for wastewater and treated wastewater. Toxicity and biological activity of the treated and untreated wastewater on marine aquatic organisms rotifer, artemia and Vibrio parahaemolyticus were investigated.
https://www.jwent.net/article_29782_6ae492bb3dfdfa5b2b67a7323bfb54b7.pdf
2018-04-01
116
127
10.22090/jwent.2018.02.003
Non-Metal Doped Tio2 Nps
Photocatalytic degradation
Reactive Blue 19 Dye
Reactive Red 76 Dye
Sol-gel process
Elsayed Talat
Helmy
stalaat41@yahoo.com
1
Environment Division, National Institute of Oceanography and Fisheries, Kayet Bey, Elanfoushy, Alexandria, Egypt
AUTHOR
Ahmed
El Nemr
ahmedmoustafaelnemr@yahoo.com
2
Environment Division, National Institute of Oceanography and Fisheries, Kayet Bey, Elanfoushy, Alexandria, Egypt
LEAD_AUTHOR
Mahmoud
Mousa
mousa_chem@yahoo.com
3
Chemistry Department, Faculty of Science, Benha University, Cairo, Egypt
AUTHOR
Esam
Arafa
eahgomaa65@yahoo.com
4
Chemistry Department, Faculty of Science, Mansoura University, 35516-Mansoura, Egypt
AUTHOR
Shady
Eldafrawy
shomirage@yahoo.com
5
Chemistry Department, Faculty of Science, Mansoura University, 35516-Mansoura, Egypt
AUTHOR
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34
35. Kassahun SK, Kiflie Z, Shin DW, Park SS. Photocatalytic Decolorization of Methylene Blue by N-doped TiO2 Nanoparticles Prepared Under Different Synthesis parameters. J. Water Environ. Nanotechnol., 2(3);2017:136-144.
35
36. Nazarpour Laghani S, Ebrahimian Pirbazari A. Photocatalytic Treatment of Synthetic Wastewater Containing 2,4 dichlorophenol by Ternary MWCNTs /Co-TiO2 Nanocomposite Under Visible Light. J. Water Environ. Nanotechnol., 2(4);2017:290-301.37. Rehman S, Ullah R, Butt AM, Gohar ND. Strategies of making TiO2 and ZnO visible light active. Journal of Hazardous Materials. 2009;170(2-3):560-9.
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37
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38
ORIGINAL_ARTICLE
Effects of operating parameters in sweeping gas membrane distillation process: Numerical simulation of Persian Gulf seawater desalination
In this communication, an advanced, simultaneous mass and heat transfer model has been developed to take a meticulous glance on the influences of different parameters on Persian Gulf seawater desalination using Sweeping Gas Membrane Distillation (SGMD) technique. This essay focuses on the increasing the distillate flux by investigation of the physical properties and feed temperature of the sweeping gas membrane distillation on the seawater desalination. The effects of operating parameters, including feed temperature, salt concentration, sweeping gas temperature, and heat transfer coefficient on the distillate flux of the Persian Gulf seawater have been investigated. The effect of feed temperature on temperature polarization has also been studied. By increasing the feed temperature from 25 oC to 60 oC, the temperature polarization increases and the polarization coefficient (TPC) decreases; for instance, for membranes with PP, the TPC decreases from 0.95 to 0.905. By increasing the feed temperature, higher fluxes are achieved for both the gas velocities. Therefore, by increasing the feed temperature from 50 oC up to 80 oC, the distillate flux grows 9 times. Also, the distillate flux for membrane with PVDF as polymer increased from 0 to 4.2 by increasing the feed temperature from 40 oC to 70 oC. The model predictions show a small error of 3.6% with the experimental data reported in literature which indicates the reliability of simulated results.
https://www.jwent.net/article_29783_3d460e82e7dc9ba163832aa24a4d3691.pdf
2018-04-01
128
140
10.22090/jwent.2018.02.004
Distillate flux
numerical simulation
Seawater
Sweeping gas membrane distillation (SGMD)
Temperature polarization
Morteza
Asghari
asghari@kashanu.ac.ir
1
Separation Processes Research Group (SPRG), Department of Engineering, University of Kashan, Kashan, Iran
LEAD_AUTHOR
Mostafa
Dehghani
dehghanii@kashan.ac.ir
2
Separation Processes Research Group (SPRG), Department of Engineering, University of Kashan, Kashan, Iran
AUTHOR
Hossein
Riasat Harami
hossein.riasat.zx@kashan.ac.ir
3
Separation Processes Research Group (SPRG), Department of Engineering, University of Kashan, Kashan, Iran
AUTHOR
Amir Hossein
Mohammadi
amir.h.mohammadi@gmail.com
4
Institut de Recherche en Génie Chimiqueet Pétrolier (IRGCP), Paris Cedex, France
AUTHOR
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65
ORIGINAL_ARTICLE
On tailored synthesis of nano CaCO3 particles in a colloidal gas aphron system and evaluating their performance with response surface methodology for heavy metals removal from aqueous solutions
Heavy metals pollution in the environment is one of the serious problems in the field of water and wastewater management. In this study; calcium carbonate nanoparticles, synthesized by an efficient and novel method, were used as an adsorbent for the removal of lead and iron from aqueous solutions. To study the mechanism of adsorption, the kinetic and isotherm models were examined. The adsorption kinetics of process was found to follow a pseudo-second-order equation. The maximum monolayer adsorption capacities of calcium carbonate nanoparticles calculated from Langmuir isotherm were found to be 1210±30 mg/g for Pb(II) and 845±8 mg/g for Fe(II) ions, respectively. The response surface methodology based on three variable Box-Behnken design was utilized to evaluate the effects of temperature (25-65 oC) and initial metal concentration (10-200 mg/L) on the sorption process. The optimum conditions for the removal process using calcium carbonate nanoparticles were found to be 200 mg/L at 25 oC. Experimental data demonstrated that a precipitation transformation mechanism rather than adsorption enhances the removal efficiency.
https://www.jwent.net/article_31136_1b3b6a39f6b621e8e1886c2394ddda21.pdf
2018-04-01
141
149
10.22090/jwent.2018.02.005
Adsorption
Box-Behnken Design (BBD)
Calcium Carbonate Nanoparticles
Pb(II) And Fe(II) Removal
Wastewater treatment
Hossein
Mohammadifard
hossein.mohammadifard@ce.iut.ac.ir
1
Department of Chemical Engineering, Isfahan University of Technology, Isfahan, Iran
AUTHOR
Mohammad C.
Amiri
amir33@cc.iut.ac.ir
2
Department of Chemical Engineering, Isfahan University of Technology, Isfahan, Iran
LEAD_AUTHOR
1. Paulino AT, Minasse FAS, Guilherme MR, Reis AV, Muniz EC, Nozaki J. Novel adsorbent based on silkworm chrysalides for removal of heavy metals from wastewaters. Journal of Colloid and Interface Science. 2006;301(2):479-87.
1
2. Gupta VK, Agarwal S, Saleh TA. Synthesis and characterization of alumina-coated carbon nanotubes and their application for lead removal. Journal of Hazardous Materials. 2011;185(1):17-23.
2
3. Zhang F-S, Nriagu JO, Itoh H. Mercury removal from water using activated carbons derived from organic sewage sludge. Water Research. 2005;39(2-3):389-95.
3
4. Boparai HK, Joseph M, O’Carroll DM. Kinetics and thermodynamics of cadmium ion removal by adsorption onto nano zerovalent iron particles. Journal of Hazardous Materials. 2011;186(1):458-65.
4
5. Argun ME. Use of clinoptilolite for the removal of nickel ions from water: Kinetics and thermodynamics. Journal of Hazardous Materials. 2008;150(3):587-95.
5
6. Fu F, Xie L, Tang B, Wang Q, Jiang S. Application of a novel strategy—Advanced Fenton-chemical precipitation to the treatment of strong stability chelated heavy metal containing wastewater. Chemical Engineering Journal. 2012;189-190:283-7.
6
7. Stojanovic A, Keppler BK. Ionic Liquids as Extracting Agents for Heavy Metals. Separation Science and Technology. 2012;47(2):189-203.
7
8. Naushad M, Mittal A, Rathore M, Gupta V. Ion-exchange kinetic studies for Cd(II), Co(II), Cu(II), and Pb(II) metal ions over a composite cation exchanger. Desalination and Water Treatment. 2014;54(10):2883-90.
8
9. Al-Zoubi H, Ibrahim KA, Abu-Sbeih KA. Removal of heavy metals from wastewater by economical polymeric collectors using dissolved air flotation process. Journal of Water Process Engineering. 2015;8:19-27.
9
10. Cui Y, Ge Q, Liu X-Y, Chung T-S. Novel forward osmosis process to effectively remove heavy metal ions. Journal of Membrane Science. 2014;467:188-94.
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11. Khan NA, Hasan Z, Jhung SH. Adsorptive removal of hazardous materials using metal-organic frameworks (MOFs): A review. Journal of Hazardous Materials. 2013;244-245:444-56.
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12. Skubal LR, Meshkov NK, Rajh T, Thurnauer M. Cadmium removal from water using thiolactic acid-modified titanium dioxide nanoparticles. Journal of Photochemistry and Photobiology A: Chemistry. 2002;148(1-3):393-7.
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13. Fu F, Wang Q. Removal of heavy metal ions from wastewaters: A review. Journal of Environmental Management. 2011;92(3):407-18.
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14. Lo S-F, Wang S-Y, Tsai M-J, Lin L-D. Adsorption capacity and removal efficiency of heavy metal ions by Moso and Ma bamboo activated carbons. Chemical Engineering Research and Design. 2012;90(9):1397-406.
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15. Al-Othman ZA, Ali R, Naushad M. Hexavalent chromium removal from aqueous medium by activated carbon prepared from peanut shell: Adsorption kinetics, equilibrium and thermodynamic studies. Chemical Engineering Journal. 2012;184:238-47.
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16. Hegazy EZ, Abdelmaksod IH, Kosa SA. Removal of Heavy Metal Quaternary Cations Systems on Zeolite A and X Mixtures Prepared from Local Kaolin. CLEAN - Soil, Air, Water. 2013;42(6):775-8.
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17. Wen J, Yi Y, Zeng G. Effects of modified zeolite on the removal and stabilization of heavy metals in contaminated lake sediment using BCR sequential extraction. Journal of Environmental Management. 2016;178:63-9.
17
18. Sud D, Mahajan G, Kaur M. Agricultural waste material as potential adsorbent for sequestering heavy metal ions from aqueous solutions – A review. Bioresource Technology. 2008;99(14):6017-27.
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19. Miretzky P, Cirelli AF. Hg(II) removal from water by chitosan and chitosan derivatives: A review. Journal of Hazardous Materials. 2009;167(1-3):10-23.
19
20. Gupta VK, Nayak A. Cadmium removal and recovery from aqueous solutions by novel adsorbents prepared from orange peel and Fe2O3 nanoparticles. Chemical Engineering Journal. 2012;180:81-90.
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21. Liu J-f, Zhao Z-s, Jiang G-b. Coating Fe3O4Magnetic Nanoparticles with Humic Acid for High Efficient Removal of Heavy Metals in Water. Environmental Science & Technology. 2008;42(18):6949-54.
21
22. Charpentier TVJ, Neville A, Lanigan JL, Barker R, Smith MJ, Richardson T. Preparation of Magnetic Carboxymethylchitosan Nanoparticles for Adsorption of Heavy Metal Ions. ACS Omega. 2016;1(1):77-83.
22
23. Kandah MI, Meunier J-L. Removal of nickel ions from water by multi-walled carbon nanotubes. Journal of Hazardous Materials. 2007;146(1-2):283-8.
23
24. Cai G-B, Zhao G-X, Wang X-K, Yu S-H. Synthesis of Polyacrylic Acid Stabilized Amorphous Calcium Carbonate Nanoparticles and Their Application for Removal of Toxic Heavy Metal Ions in Water. The Journal of Physical Chemistry C. 2010;114(30):12948-54.
24
25. Ma X, Li L, Yang L, Su C, Wang K, Yuan S, et al. Adsorption of heavy metal ions using hierarchical CaCO3–maltose meso/macroporous hybrid materials: Adsorption isotherms and kinetic studies. Journal of Hazardous Materials. 2012;209-210:467-77.
25
26. Mohammadifard H, Banifatemi SS, Amiri MC. Growing Innovative Calcium Carbonate Morphologies by Utilizing the Colloidal Gas Aphron System as a Surfactant-Based Template Method. Chemical Engineering Communications. 2016;203(9):1165-72.
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27. Stephan W. Foams and biliquid foams-aphrons. Chister, New York, Brisbane, Toronoto, Singapore: John Wiley & Sons, 1987, 236 S., ? 29.50, ISBN 0-471-91685-4. Acta Biotechnologica. 1989;9(1):68-.
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28. Amiri MC, Sadeghialiabadi H. Evaluating the stability of colloidal gas aphrons in the presence of montmorillonite nanoparticles. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2014;457:212-9.
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29. Amiri M. Effect of gas transfer on separation of whey protein with aphron flotation. Separation and Purification Technology. 2004;35(2):161-7.
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30. Yuh-Shan H. Citation review of Lagergren kinetic rate equation on adsorption reactions. Scientometrics. 2004;59(1):171-7.
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31. Ho Y. Review of second-order models for adsorption systems. Journal of Hazardous Materials. 2006;136(3):681-9.
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32. Frimmel FH, Huber L. Influence of humic substances on the aquatic adsorption of heavy metals on defined mineral phases. Environment International. 1996;22(5):507-17.
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34. Aziz HA, Adlan MN, Ariffin KS. Heavy metals (Cd, Pb, Zn, Ni, Cu and Cr(III)) removal from water in Malaysia: Post treatment by high quality limestone. Bioresource Technology. 2008;99(6):1578-83.
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35. Al-Degs YS, El-Barghouthi MI, Issa AA, Khraisheh MA, Walker GM. Sorption of Zn(II), Pb(II), and Co(II) using natural sorbents: Equilibrium and kinetic studies. Water Research. 2006;40(14):2645-58.
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37
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38
ORIGINAL_ARTICLE
Modification of natural zeolite for effective removal of Cd(II) from wastewater
In the current research work the Iranian natural zeolite (clinoptililite) was modified with Cobalt Hexacyanoferrate nanopatricles. The natural and Cobalt Hexacyanoferrat modifed zeolites were characterized by FTIR and SEM techniques and were empolyed as an adsorbent for removal Cd(II) ions from aqueous sloution. The adsorption expriments were performed in bach mode. The Cd(II) sorption capacity of Cobalt Hexacyanoferrat modified zeolite was 51 mg g-1. The effect of influceing factors such as time, temperature and initial concentration were investigated. A fast sorption was observed in the initial contact time and equilibrium was achieved in less than 100 min. The equilibrium adsorption data for Cd (II) were better fitted to the Longmuir adsorption isotherm model. The increase in temperature has a slight positive effect on the uptake of Cd(II) ions. The results indicated that the Cobalt Hexacyanoferrate nanopatricles modified natural zeolite has effective potential for the adsorption of Cd(II) from the wastewater.
https://www.jwent.net/article_29781_4eb3f229c6a4d7ebcc87f08b54aac520.pdf
2018-04-01
150
156
10.22090/jwent.2018.02.006
Zeolite
Nanoparticle
Cobal hexacyanoferrate
Adsorptiom
Clinoptilolite
Taher
Yousefi
taher_yosefy@yahoo.com
1
Materials and Nuclear Fuel Research School, Nuclear Science and Technology Research Institute, Tehran, Iran
LEAD_AUTHOR
Hamid Raza
Moazami
a.a1393@gmail.com
2
Physics and Accelerators Research School, Nuclear Science and Technology Research Institute, Tehran, Iran
AUTHOR
Hamid Reza
Mahmudian
s.ah20014@gmail.com
3
Department of Chemical Engineering, Faculty of Engineering, University of Tehran, Tehran, Iran
AUTHOR
Meisam
Torab-Mostaedi
mmostaedi@aeoi.org.ir
4
Materials and Nuclear Fuel Research School, Nuclear Science and Technology Research Institute, Tehran, Iran
AUTHOR
Mohammad Ali
Moosavian
a.g1393@gmail.com
5
Department of Chemical Engineering, Faculty of Engineering, University of Tehran, Tehran, Iran
AUTHOR
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1
2. Tanzifi M, Kolbadi nezhad M, Karimipour K. Kinetic and Isotherm Studies of Cadmium Adsorption on Polypyrrole/Titanium dioxide Nanocomposite. Journal of Water and Environmental Nanotechnology. 2017;2(4):265-77.
2
3. Barsbay M, Kavaklı PA, Tilki S, Kavaklı C, Güven O. Porous cellulosic adsorbent for the removal of Cd (II), Pb(II) and Cu(II) ions from aqueous media. Radiation Physics and Chemistry. 2018;142:70-6.
3
4. hassanzadeh Siahpoosh Z, Soleimani M. Trace Cd(II), Pb(II) and Ni(II) ions extraction and preconcentration from different water samples by using Ghezeljeh montmorillonite nanoclay as a natural new adsorbent. Journal of Water and Environmental Nanotechnology. 2017;2(1):39-51.
4
5. Rengaraj S, Yeon K-H, Kang S-Y, Lee J-U, Kim K-W, Moon S-H. Studies on adsorptive removal of Co(II), Cr(III) and Ni(II) by IRN77 cation-exchange resin. Journal of Hazardous Materials. 2002;92(2):185-98.
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6. Dianati-Tilaki RA, Ali R, editors. Study on removal of cadmium from water environment by adsorption on GAC, BAC, and biofilter. Diffuse Pollution Conference, Dublin 8B Ecology; 2003.
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7. Li R, Liang W, Li M, Jiang S, Huang H, Zhang Z, et al. Removal of Cd(II) and Cr(VI) ions by highly cross-linked Thiocarbohydrazide-chitosan gel. International Journal of Biological Macromolecules. 2017;104:1072-81.
7
8. Soltani R, Dinari M, Mohammadnezhad G. Ultrasonic-assisted synthesis of novel nanocomposite of poly(vinyl alcohol) and amino-modified MCM-41: A green adsorbent for Cd(II) removal. Ultrasonics Sonochemistry. 2018;40:533-42.
8
9. Guo S, Jiao P, Dan Z, Duan N, Zhang J, Chen G, et al. Synthesis of magnetic bioadsorbent for adsorption of Zn(II), Cd(II) and Pb(II) ions from aqueous solution. Chemical Engineering Research and Design. 2017;126:217-31.
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29
ORIGINAL_ARTICLE
Optimization of process variables by response surface methodology for methylene blue dye removal using Spruce sawdust/MgO nano-biocomposite
The purpose of this investigation is to study the influence of Spruce sawdust (SD) coated by magnesium oxide (MgO) nanoparticles in the removing of methylene blue (MB) from an aqueous solution which is in a batch system. The adsorbent was characterized by FTIR, FE-SEM, BET and XRD analysis. The high adsorption potential of SD-MgO nano-biocomposite was revealed by these findings, therefore, it is usable for dye-containing wastewater treatment. By investigating the impact of particular conditions like MB concentrations, the dose of adsorbent and pH, it became possible to confirm the effectiveness of the process. The OOP (which stands for Optimum Operating Parameters) were evaluated by RSM (which stands for Response Surface Methodology) which is based on BBD (Box-Behnken design) and is used for removing MB dye. The adsorbent dosage is the highest effective degree of the individual factor on MB removal. Maximum removal of MB dye was detected at pH 11 with 3.50 g L-1 adsorbent dosage. The surface area of 0.873 m2 g-1 and mesoporous adsorbent prepared gave good adsorption capacity of 26.657 mg g-1 for MB. Furthermore, in order to predict the empirical variables’ significance, the variances’ analysis (ANOVA) was used. The predicated removal efficiency which is proved to be the potency of the process and its effectiveness was found to be 94.05%. Different equilibrium and kinetic models were utilized to the experimental data. Both Pseudo-second order kinetic model and Freundlich adsorption isotherm showed the better fitness to the experimental data.
https://www.jwent.net/article_31138_d57911f593eeb5241490294d5740519e.pdf
2018-04-01
157
172
10.22090/jwent.2018.02.007
Adsorption
Box-Behnken Design
Dye
Mgo Nanoparticles
Nano-Biocomposites
Seyed Hassan
Sharifi
h.sharifi@sanru.ac.ir
1
Wood and Paper Science Department, Faculty of Natural Resources, Sari Agricultural Sciences and Natural Resource University, Sari, Iran
LEAD_AUTHOR
Hassan
Shoja
h.shojae1373@gmail.com
2
Wood and Paper Science Department, Faculty of Natural Resources, Sari Agricultural Sciences and Natural Resource University, Sari, Iran
AUTHOR
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62
ORIGINAL_ARTICLE
Evaluation and synthesis of Nano-pore Hydroxysodalite (HS) zeolite membranes: Application to pervaporation of Ethanol/water mixture
Effect of crystallization time and temperature on the membrane structure and performance has been investigated for Nano-pore Hydroxysodalite (HS) zeolite membranes. Molar composition of the starting gel of the HS zeolite membranes were: SiO2/Al2O3=1.0-5.0, Na2O/Al2O3=15-65, and H2O/Al2O3=500-1500. X-ray diffraction (XRD) patterns of the membranes exhibited peaks corresponding to the support and the zeolite. The crystal species was characterized by XRD and the morphology of the supports subjected to crystallization was characterized by Scanning Electron Microscopy (SEM). Separation performance of HS zeolite membranes was studied for water-Ethanol mixtures using pervaporation (PV). The membranes showed good selectivity towards water in the water-Ethanol mixtures. Water permeates faster because of its preferential adsorption into the Nano-pores of the hydrophilic zeolite membrane. In PV of water-Ethanol mixtures, the membrane exhibits a hydrophilic behavior, with a high selectivity towards water and a good flux. The best flux and separation factor of the membranes were 2.05 kg/m2.h and 10000, respectively. Effect of operating condition (temperature, flow rate and pressure) on the membrane performance was investigated for HS zeolite membranes grown onto seeded mullite supports. Finally, a comprehensive 2D model was developed for the PV of water-Ethanol mixture through HS zeolite membrane using Finite Element Method (FEM). Effect of varying dimensional factors, temperature and feed flow rate on the PV performance was studied. The proposed model was masterfully capable of predicting concentration distribution within two sub-domains of feed and membrane.
https://www.jwent.net/article_29780_0edb527ca1f5982e64fd0ab098c4097c.pdf
2018-04-01
173
190
10.22090/jwent.2018.02.008
Ethanol
FEM
Hydroxysodalite
Pervaporation
Zeolite Membrane
Mansoor
Kazemimoghadam
mzkazemi@gmail.com
1
Department of Chemical Engineering, Malek-Ashtar University of Technology, Tehran, Iran
LEAD_AUTHOR
Zahra Amiri
Rigi
amiri.z.1394@gmail.com
2
Department of Chemical Engineering, South Tehran Branch, Islamic Azad University, Tehran, Iran
AUTHOR
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