Mahmood Hajiani; Efat Ezami; Mohammad Reza Rezaei
Abstract
Fe3O4/ ZnO/Ag magnetic nanocomposite was synthesized for the first time and its ability was evaluated for photocatalytic degradation of albumin in aqueous solutions under UV-A light. The resulting nanoparticles were then characterized using X-ray diffraction (XRD), scanning electron microscopy (FESEM), ...
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Fe3O4/ ZnO/Ag magnetic nanocomposite was synthesized for the first time and its ability was evaluated for photocatalytic degradation of albumin in aqueous solutions under UV-A light. The resulting nanoparticles were then characterized using X-ray diffraction (XRD), scanning electron microscopy (FESEM), vibration magnetometer (VSM), and Fourier infrared (FTIR). The effects of some parameters such as pH, initial albumin concentration, catalyst concentration, and temperature were also investigated in the photodegradation of albumin. The results showed that the maximum removal of albumin was obtained at pH 9, catalyst concentration of 0. 5 g/l, initial albumin concentration of 150 mg/l, and room temperature in 90 min. Under the optimum conditions, the total amount of organic carbon (TOC) was 56%. Kinetic degradation experiments followed the pseudo-first-order kinetic model with a constant rate (k) of 0.0255 min-1. Therefore, due to the high performance of Fe3O4/ ZnO/Ag magnetic nanocomposite in the degradation of albumin as well as its easy synthesis and separation with an external magnetic field, it can be used as a suitable and environmentally friendly catalyst for the degradation of organic and resistant pollutants in the wastewater.
Azam Gholami; Mahmood Hajiani; Mohammad Hossein Sayadi Anari
Abstract
Contaminants of emerging concern or simply emerging contaminants have been considered as a critical environmental issue in recent decades. These compounds have not routinely controlled and monitored; therefore they have posed risk to health of human and environment. Drugs are considered as one of the ...
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Contaminants of emerging concern or simply emerging contaminants have been considered as a critical environmental issue in recent decades. These compounds have not routinely controlled and monitored; therefore they have posed risk to health of human and environment. Drugs are considered as one of the most important emerging pollutants. They introduce to environment form different sources such urine, human excretion, livestock, poultry, pharmaceutical, and hospitals. Although they are in trace levels, they are not biodegradable. They cannot be removed by conventional treatment processes. .. Advanced oxidation processes (AOPs) have been designed to address the deficiency of conventional methods in removal of emerging pollutants. Production of highly reactive hydroxyl radicals is the base of AOPs. These very reactive radicals effectively oxidize emerging pollutants such as drugs. Among different approach of AOPs, photocatalytic degradation has been successfully applied to mitigate the side effects of emerging contaminants. The ability of photocatalytic process in removal of Clindamycin hydrochloride (CLM) from aqueous solutions in the presence of UV/TiO2 was studied. The effects of various parameters such as adsorption, photolysis, pH, catalyst dosage, initial concentration of antibiotic, and radiation time were investigated in a batch photoreactor. Results showed that photolysis and adsorption had a negligible contribution to the clindamycin removal. The maximum clindamycin removal rate was obtained under optimal conditions, such as pH of 5, 0.5 g/l of TiO2, initial clindamycin concentration of 2 /L. This optimum condition was achieved during 90 minutes.. The CLM photocatalytic degradation kinetics showed that CLM degradation follows the pseudo-first-order kinetics.