Mohammad Ghorbanpour; Atabak Feizi
Abstract
The aim of the present study is to synthesize and characterize Fe-doped TiO2 nanoparticles prepared by molten salt method using a precursor of a solid mixture of TiO2 powder and FeCl3. As far as this study is concerned, this is the simplest method that has been reported so far for the synthesis of Fe-doped ...
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The aim of the present study is to synthesize and characterize Fe-doped TiO2 nanoparticles prepared by molten salt method using a precursor of a solid mixture of TiO2 powder and FeCl3. As far as this study is concerned, this is the simplest method that has been reported so far for the synthesis of Fe-doped TiO2 nanoparticles. Pure TiO2 nanoparticles and 0.5, 1 and 3 wt % Fe-doped TiO2 samples were prepared. Characterization of prepared nanoparticles was done by UV-Vis diffusion reflection spectroscopy (DRS), scanning electron microscopy (SEM), X-ray diffraction (XRD) and Energy-dispersive X-ray spectroscopy (EDX). SEM and XRD analysis of the samples indicated the presence of anatase spherical-shaped TiO2 particles. The results of EDX study confirmed the presence of Fe in all of the samples. According to DRS results, the band gap energy of Fe doped TiO2 nanoparticles decreased with increasing Fe concentration from 3.1 eV for pure TiO2 to 3.0- 2.80 eV for Fe-doped TiO2. The photocatalytic activity was also checked. It was found that, the photocatalytic activity of Fe-doped nanoparticles was higher than pure TiO2. The maximum degradation activity of 69% was obtained at the Fe doping content of 0.5 wt%.
Bahareh Hakimi; Mohammad Ghorbanpour; Atabak Feizi
Abstract
ZnO/bentonite photocatalyst was synthesized using different methods, including: precipitation, liquid-state ion exchange (LSIE) and solid-state Ion exchange (SSIE) methods. In most studies done so far, LSIE and precipitation method have been used to prepare composites. The SSIE is a new method. The purpose ...
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ZnO/bentonite photocatalyst was synthesized using different methods, including: precipitation, liquid-state ion exchange (LSIE) and solid-state Ion exchange (SSIE) methods. In most studies done so far, LSIE and precipitation method have been used to prepare composites. The SSIE is a new method. The purpose of this research is to produce nanocomposites with each of these methods and compare their photocatalytic activity. The physicochemical properties of the prepared photocatalysts were determined by scanning electron microscope (SEM), energy dispersive X-ray (EDX) and diffusive reflective spectroscopy (DRS) analysis. The Photocatalytic activity was evaluated by degradation of methyl orange (MO) with the prepared photocatalysts. SEM images showed that the ZnO particles were successfully distributed on the bentonite in the samples prepared by precipitation method. Nevertheless, after ion exchange-based methods, no particles were formed on the bentonite surface. This is because of very small size of ZnO particles which in the interlayer space of bentonite. The EDX and DRS analysis confirmed the formation of composites. The photodegradation of MO were 84, 85 and 87% for the composites prepared by LSIE, SSIE and precipitation methods, respectively. Ultimately, the photocatalytic composites prepared by the solid-state method are very bright due to their simple production, low price and short time due through direct heating of the reaction.